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 Chem 1315 (Urgent)
Posted: October 16, 2008 06:44 pmTop
   
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IRC Nickname: Matt|Multi
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Yay Chemistry! Show work please. All problems from the 2 quizzes I have that are due this evening.

Question 1 (10 points)
What is the wavelength (nm) of the energy that corresponds to the transition from n = 4 to n = 7 in a hydrogen atom?

Question 2 (10 points)

What is the wavelength of light (nm) having a frequency of 7.41 x 1014 Hz?

Question 3 (10 points)
What is the wavelength (nm) of a photon with a kinetic energy of 6.74 x 10-19 J?


Arrange the following set of ions in order of decreasing atomic radii.

Al3+, Ga3+, Ca2+, Rb+, K+


Arrange the following elements in order of decreasing first ionization energy.

Be, Ca, Cs, Mg, K

a. Mg > Be > Ca > K > Cs
b. Cs > K > Ca > Be > Mg
c. Ca > Mg > Be > K > Cs
d. Be > Mg > Ca > K > Cs
e. Ca > Mg > Be > Cs > K

Given the following hypothetical equations,

2A + B --> 3C + 2D H = -52.5kJ

C --> B H = -71.8kJ

2E--> B H = -88.6kJ,

what is the enthalpy change (kJ) for the following reaction?

A --> D + 2E

10.6 g of ice at -2.6oC is added to 139 mL of water at 38.2oC. What is the final temperature (oC) of the mixture?
 
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Posted: October 16, 2008 09:01 pmTop
   
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First 3 I don't know yet, but here's what i can do:

Arrange the following set of ions in order of decreasing atomic radii.

Al3+, Ga3+, Ca2+, Rb+, K+
Al, K, Ca, Ga, Rb


Arrange the following elements in order of decreasing first ionization energy.

Be, Ca, Cs, Mg, K

a. Mg > Be > Ca > K > Cs <-this one
b. Cs > K > Ca > Be > Mg
c. Ca > Mg > Be > K > Cs
d. Be > Mg > Ca > K > Cs
e. Ca > Mg > Be > Cs > K

Given the following hypothetical equations,

2A + B --> 3C + 2D H = -52.5kJ

(times 3) C --> B H = -71.8kJ (times 3)

(times -2)2E--> B H = -88.6kJ (times -2 as well)

____________________________

2A + B ---> 3c + 2D H = -52.5kJ
3C --> 3B H = -215.4kJ
2B --> 4E H = 177.2kJ

_______________________________
(halve) 2A --> 4E+2D H = -90.7kJ (halve too)
A --> 2E + D H = -45.35kJ

what is the enthalpy change (kJ) for the following reaction?

A --> D + 2E

10.6 g of ice at -2.6oC is added to 139 mL of water at 38.2oC. What is the final temperature (oC) of the mixture?

Don't know, sorry

That's all I could do. Hope it helps.

You might wanna double check it just in case.
 
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Posted: October 16, 2008 10:43 pmTop
   
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IRC Nickname: Matt|Georgio9
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The first three are are just things you plug into equations. I did this all last year. I'd help you out but I don't know the equations off the top of my head for them.
the equation for hash.png2 is

C = (wave length)(frequency)

where C is the speed of light.

3x10^8 m/s = (wave length)(7.41 x 10^14 Hz)
wave length = 4.0485829 x 10 ^ -7 m


 
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Posted: October 16, 2008 10:57 pmTop
   
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Ok for your last question, i don't have the constants but this is how you do it

LEFT SIDE:
q = mc(T2 - T1) right?

Ok so thats your left side, that tells you what your final temperature of the water will be. m is the mass of the water, c is the heat capacity constant, T1 is your initial temperature (38C) and T2 is your new temperature.

RIGHT SIDE:

q = A + B + C
q = mc(T) + mc(T2 - T1) + Hn

where term A is the energy to raise the temperature from -2.6C to the 0C, the melting point. term B is the energy to raise the temp from 0 to the equilibrium temp of the water surrounding. Term C is energy required to change the ice to water (heat of fusion).

Make the right side = left side and there you go.
 
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Posted: October 16, 2008 11:53 pmTop
   
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You use a combination of a couple equations to get 1.

First one is E= R(1/(ni)^2 - 1/(nf)^2)
where R is the rydberg constant for hydrogen

Then, to find the wavelength, you plug the value you got for E into
E=hc/(wavelength) , where h is Planck's constant and c is the speed of light. From there, you can solve for the unknown value for wavelength.
 
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Posted: October 17, 2008 12:53 amTop
   
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Sorry but I struggled long and hard for my B- in Chemistry......I forgot it all that summer too hash.png
 
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Posted: October 17, 2008 02:00 amTop
   
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So for clarification, I ended up getting all but the last problem on my own, just had to read the book (Which I had been neglecting to do) hash.png.

Just took my midterm, think I did fairly well on it.
 
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Posted: October 17, 2008 11:29 pmTop
   


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QUOTE (Multikill529 @ October 17, 2008 02:00 am)
Just took my midterm, think I did fairly well on it.

A midterm in october? I feel bad for you
 
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Posted: October 18, 2008 12:48 amTop
   
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QUOTE (Mangomaniac2 @ October 17, 2008 11:29 pm)
QUOTE (Multikill529 @ October 17, 2008 02:00 am)
Just took my midterm, think I did fairly well on it.

A midterm in october? I feel bad for you

Yep. Midterms for all my classes are this week and next. Also, got an 80% on that chemistry test, was nowhere NEAR as hard as we thought it would be.
 
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Born at sea, baptized in blood your fame will never die. Your Division is one of the best if not the best division in the history of American arms -Gen George S Patton on the 45th Infantry Division

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Posted: October 19, 2008 12:52 amTop
   
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QUOTE (Mangomaniac2 @ October 17, 2008 11:29 pm)
QUOTE (Multikill529 @ October 17, 2008 02:00 am)
Just took my midterm, think I did fairly well on it.

A midterm in october? I feel bad for you

... all my midterms are in october lol. I had one last wednesday and two more this thursday and the other is on friday, which is my birthday....bastards

second year is a row thats happened. Anyways its in the morning soooooooo i'm going to go to the engineering pub/bar afterwards lol. 19 = legal in Canada bish.
 
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